Book Name: [PDF] Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by Shilov and Shul’ pin
Category: Organic Chemistry
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Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by Shilov and Shul’ pin

Title: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes
Editor: Alexander E. Shilov
Georgiy B. Shul’pin
Volume: 21st
Publisher: Springer Publications
Length: 550 pages
Size: 26.2 MB
Language: English

Book Description:

This monograph is devoted to the activation and various transformations of saturated hydrocarbons (alkanes), i.e. reactions accompanied by the C–H and C–C bond cleavage. Alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for the chemical industry. On the other hand, these substances are known to be the least reactive organic compounds. Special attention is paid to the recently found alkane activations in the presence of metal complexes, which are described in more detail. In addition to the reactions of saturated hydrocarbons which are the main topic of this book, the activation of C–H bonds in arenes and even olefins and acetylenes are considered. The monograph will be useful not only for those who are interested in the activation of alkanes and other hydrocarbons by metal complexes, but also for specialists in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. Some parts of the monograph will be of interest for specialists in inorganic and organic chemistry, theoretical chemistry, biochemistry and even biology, and also for those who work in the petrochemical industry, industrial organic synthesis and biotechnology.

Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes

Author(s): Alexander E. Shilov, Georgiy B. Shul’pin (auth.)

Series: Catalysis by Metal Complexes 21

Publisher: Springer Netherlands, Year: 2002

ISBN: 978-0-7923-6101-5

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[PDF] Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by Shilov and Shul’ pin Table Of Contents

Introduction….Pages 1-7
Processes of C-H Bond Activation….Pages 8-20
Hydrocarbon Transformations That do not Involve Metals or Their Compounds….Pages 21-75
Heterogeneous Hydrocarbon Reactions with Participation of Solid Metals and Metal Oxides….Pages 76-126
Activation of C-H Bonds by Low-valent Metal Complexes (“The Organometallic Chemistry”)….Pages 127-199
Hydrocarbon Activation by Metal Ions, Atoms, and Complexes in the Gas Phase and in a Matrix….Pages 200-218
Mechanisms of C-H Bond Splitting by Low-valent Metal Complexes….Pages 219-258
Activation of Hydrocarbons by Platinum Complexes….Pages 259-317
Hydrocarbon Reactions with High-valent Metal Complexes….Pages 318-370
Homogeneous Catalytic Oxidation of Hydrocarbons by Molecular Oxygen….Pages 371-429
Homogeneous Catalytic Oxidation of Hydrocarbons by Peroxides and Other Oxygen Atom Donors….Pages 430-465
Oxidation in Living Cells and its Chemical Models….Pages 466-522

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